To get the most accurate results, it's best to check the density of your biodiesel. This still ends up being cheaper than regular diesel, since you add 20% methanol for the amount of WVO you use.Safety equipment you'll need:-chemical resistant p100 respirators Got 2 at Lowes for $25-$30 each-lab goggles-chemical resistant glovesWhat you'll need for the titration:-Isopropyl alcohol get this at an auto parts store-distilled water-a very tiny bit of your catalyst (NaOH or KOH)-a sample of your WVO-3 oral syringes Get these at the drug store-Phenol Red indicator (like for testing your pool water). Measure out the x of hydrochloric acid, and make up a solution of 1 liter of distilled water and this x ml of your hydrochloric acid. However, glycerin is the byproduct of soap making and is present in most all natural soaps. It has water in it, and will ruin your reaction, avoid using this at all costs. Strain the glycerin to remove any impurities and then return it to the pot. (PPM of Soap) x (Liters of Biodiesel) x (8.6) / 1000 = Grams of Magnesol Required. We also carry all of the syringes & safety equipment you may need such as lab coats, chemical resistant gloves, beakers and safety glasses. If you spill either chemical on your skin, rinse it off immediately with water. The first thing required before reacting your BDG into soap is to work out something called a saponification value (SAP) value. The most common method of biodiesel production is a reaction of vegetable oils or animal fats with methanol or ethanol in the presence of sodium hydroxide(which acts as a catalyst). If this is not done, the water will later react with the vegetable oil in the reaction and make soap, shown below. There are several people (including us) that sell Biodiesel glycerin soap on a regular basis. One way you can part with all that glycerin is by converting a portion of it into soap. leave the intake valve closed for now. Hook this up the same way you did the carboy with the oil. Once it turns bright pink and stays that way you need to count exactly how many milliliters of lye/water solution you used to neutralize the acidity of the oil. Also, you use different amounts depending on which you go with. Pre-dilution method may effect final dilution. well, KOH dissolves better in the methanol and NaOH tends to make the final byproduct (glycerin) more congealed. 2022 Soap Queen Site Design by Emily White Designs, The best soap supplies on the internet are found at Bramble Berry. Use it on your hands, arms, & legs to avoid dry, flaky skin (the glycerin in the soap is a natural moisturizer). Biodiesel Blend, n - a blend of biodiesel fuel meeting ASTM D 6751 with petroleum-based diesel fuel, . These are biodiesel glycerin samples from several different biodiesel batches that have had the saponifiable ingredients separated from the glycerin. (now, I've tried to make this neutral enough so that I don't spark a huge debate, but, in advance, sorry if i offend anyone). Allow the soap 2-4 weeks to cure. Thank the good folks who are against contraception and work so hard for disease control for that. 3 years ago container to make 1 -inch-thick soap. The water content of acid oils was 3.15% and 0.8%. Tutorials on soapmaking, bath fizzies, lotions and more, April 6, 2007 Filed Under: Cold Process Soap. I get a lot of questions about soap and toiletries. This is probably due to the fact that it is 100% glycerin which is not entirely saponifiable by lye. I do not personally recommend making soap with the byproduct glycerin from biodiesel manufacturing as I dont think its entirely clean and pure and has some extra things like methanol in it. Biofuels from algae does sound promising, but then there will be impacts on marine environments. Image titled Make Lye Soap from Biodiesel By products Step 10 Make sure it's all very tight and secure, you don't want this stuff leaking. Now we can use this information to tell us how much NaOH to use in the reaction. All you need to do is figure out a way to package the soap so that it looks nice and appealing and then come up with a way to find a market for it. Test your oil to determine its acidity 6. Some of our customers havecreated websites where they sell their soap. I'm dry-washing my fuel. 32 oz. Whether you make the soap for yourself or end up selling it to others to share in the fun, we cant think of a better way to responsibly and effectively get rid of the glycerin by-product from the Biodiesel making process. You may see it start to foam. Start by measuring out 1 gram of NaOH and mixing that with one liter of the distilled water. Continue to heat the mixture of glycerin, catalyst, and water as you stir slowly and evenly for 10-20 minutes or until the mixture begins to thicken. Reply End of acid stage (note darker colour). In this video, Rick Knicely from the Knice-N-Clean Soap Company, shows how to make Biodiesel Glycerin Soap using the cool Biodiesel Glycerin Soap Making Kit. Abstract and Figures. How are biofuels made step by step? This is where we test the acidity of the oil, by measuring the free fatty acids, to see how much NaOH is needed for the reaction. Instructable #2 in my series on biodiesel. 6. Once the soap is made, be prepared to make A LOT MORE of it. A small homebrewing operation can fit in the corner of a garage, within the. 30% fats and 70% oil -- lumps of semi-hard fat remain after water boil-off. Lastly, Methoxide, the substance produced when you mix your catalyst with the methanol, is an extremely toxic nerve agent. To assist in the BDG soaping process and to make it a bit easier to make quality BDG soaps you can use the KNC SAP process outlined on my blog. 4) Continue to stir until the mixture gets thick (if making bars) This is a .01N solution. Makes you wonder what would it take to get people to ride bikes instead. Pour the mixture into a shallow container. Remove the mixture from the heat and stir for another 10 minutes. 12. Canola oil: Affordable and widely available, canola oil creates a white bar of soap. Thanks (popping over to your site now). Reply Dry-washing uses Magnesol, and it uses no water.My next instructable will deal with the washing process. 11 years ago The recipe above will be soft but will lather decently and last much longer than 100% glycerin soap. Everyone Ive ever spoken with reports that once they give a few bars out, the folks that they gave it to come back & want more and more of it. Heat the oil to 130 degrees F. (you can open the drain valve, get a quick sample, and use a quick-read thermometer to check. ) Ok so here is my question.I have read a few articles on using the biodiesel byproducts for soap making. Your email address will not be published. One person I know simply lets it settle for a few days and disposes of the sludge that settles on the bottom. Coconut Oil 16 oz. Tilt the carboy to make sure all the methoxide drains out. Give it a try! Biodiesel will run in a diesel engine, I don't recommend trying it in a gas engine. ). This is the most dangerous part of making the fuel.Measure out 20% of the total volume of oil worth of methanol into a carboy with a vent. I personally would not ever use this glycerin as an ingredient in soap but there are a lot of people that would like to, purity concerns be damned. There may be some unreacted catalyst, too. A gallon of oil will yield about a gallon of biodiesel. Ive personally seen it take out some of the worst stains out of kids clothes that commercially bought soap detergents couldnt even touch. 2 Add 3.5 grams (0.02 oz) of lye. It's not rocket surgery, it's market economics 101. Store the soap in zipper plastic bags with wax paper between the bars so they dont stick together. Divide the weight by 100 to get the density. 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Also, both bar and liquid BDG soaps can benefit from adding ingredients to help them lather better. All you need is a few common chemicals and some equipment you can easily buy or make yourself. Much of the same processes are used and most people report that it comes very naturally. Also due to vegetable oil being renewable, the . In addition to saponifiable elements, BDG already contains soaps that were created during the biodiesel production process. You need to learn to make these 5 items After a careful study I could detect that these five items could be significant to be stockpiled, or even better, homemade: Vegetable oil Vinegar Biodiesel Soap and toothpaste Alcohol Lets see why I have identified these as important. If you introduce it too quickly it will make soap. Purer methanol means better biodiesel and less soap in the biodiesel process. Heat it to 175 F (79 C) if you made your biodiesel from ethanol. From 3% or 4%, up to 10% or 15% FFAs, a common approach is to use vacuum distillation to remove the FFAs from the oil. I am posting my thoughts on this interesting subject for all to see, in the hopes that it educates and possibly stems the endless tide of I know this is a really strange question, but I make biodiesel and I was wondering . emails. The color can also be changed to your liking as well through dyes and bleaching agents. You can think of it as just a really bad batch of soap, one that is undersaponified and unbalanced. These products have all been carefully selected and tested with biodiesel glycerin to ensure top notch soaps that are environmentally friendly. How to Make Biodiesel You want to prepare the biodiesel in a room that is at least 70 degrees F because the chemical reaction will not proceed to completion if the temperature is too low. If youre interested in making soap, there are people always available on the discussion forums ready to help you and if you get the guides, the author is great at offering help & support via email. Palm Oil Probably not a bad idea, and I may do this in the future. Not what we're shooting for here. After 12-14 hours it should be separated out. About: Ask me questions. I just finished making my first batch of BioDiesel. SAP VALUE Getting the proper reaction will require that it 20% methanol. 4. such is life for those outside the sweet spot areas where walking, bicycling, or even train commuting is an option. But you know I use biofuel for most of my transport needs: I eat food and ride a bike. Heres just a few examples of soap of different colors. You'll be amazed how well it works! We are using glycerin, lye, and water to make soap. Once produced, biodiesel contains several impurities such as soap and glycerin. It was going to be thrown away anyways; hence the term "waste". 8. In some cases people even have reported calluses just melting away after using the soap theyve made. The process for making biodiesel uses an oil, a catalyst, and an alcohol. 7. I purchased your book(making bio diesel soaps).This book heaps me so much.I would like to know how can we make hybrid soaps(making bar soap from potassium based bio glycerin).please reply as soon as possible .I am not able to find out this thing in book. You can use a lye calculator: https://www.brambleberry.com/Pages/Lye-Calculator.aspx to determine how to much lye you need for how much oil you have. While the methanol is being blended, you'll need to make . It will cause blindness or death if ingested; one way it's absorbed into your body is through your skin, so simply handling the stuff with bare hand is bad for you. The main goal is to proof that one can make soap(greener product) from used oil i.e biodiesel. on Introduction. As well, biodiesel can be used as heating oil and as fuel (Mushrush et al., 2001; Wardle, 2003). Cut the soap into 45 bars that measure 3-by-2 inches (5.1 cm). on Introduction. If you have ever made bar soap from BDG you may have found that it can be fairly soft unless the oil you used to make your biodiesel came from saturated oils such as coconut, lard, tallow or hydrogenated vegetable oil. 3. In this article will dig into the nitty gritty of what it takes to get started turning your nasty black stuff into bars or jars of this incredible soap! Using biodiesel glycerin can greatly reduce the production costs of making soap without sacrificing quality. Click here to see the discussion forum on soap recipes & more! In this case: Waste vegi oil (WVO), NaOH (lye), and methanol. Leave the element on. Drain the fuel into a separate bucket/container. 10. After the exchange takes place, the free fatty acid portion of the soap molecule is soluble in the biodiesel and passes through the resin bed. About the farmers switching to it, most like there land, not the ocean, I'm sure that a new job niche will only do good things for the economy 5 from 17 votes. Please please please please learn about safety with making lye based soap (goggles, gloves, no kids, no pets, etc) before you start. If you're using more than 5 gallons of oil you obviously will need to disconnect the hose and repeat more than once. 5) Pour the mixture into the molds and smooth it out Turn on the pump and make sure the glycerin drain and out-take valve are both closed, so oil doesn't come shooting out. Can I Sell The Stuff? To add lather to both your bar and liquid soaps you might think about using coconut oil, palm kernel oil, castor oil, myristic acid and/or lauric acid. By adding other whole oils or fatty acids you can add the missing properties to your BDG soaps to create the desired soap you want to create. If water could be eliminated, then there would be no soap . This gives you a 1/1000 solution. 2. For hardening bar soaps you might think about using coconut oil, palm kernel oil, lard, tallow, stearic acid and/or palmitic acid. We partnered up with him and now have this guide available on our site to purchase. These ingredients may include Mono-glycerides, Di-glycerides, Unreacted Oil and/or biodiesel. Avoid burnt oil, as this will not react to make biodiesel. If you are like the rest of us that make biodiesel, your biodiesel glycerin (BDG) may be piling up adding to the proverbial glycerin lake. Before you make the fuel you need to filter your oil. Growth of An Industry. We even offer a Biodiesel Glycerin Soap Making Kit to help you get started! example 1, The other way is to put it under vacuum and use a methanol recovery still to get it all out. lol, perhaps your problem was taking a job that required communing 100 miles a day. Palm Oil 32 oz. ). Use a knife (carefully) or some piano wire on two posts (like a cheese cutter) to cut the soap into more manageable pieces. Biodiesel/diesel fuel blends up to B7 are covered by EN 590. If everyone switches to biofuels we can kiss the last of the world's rainforests goodbye. Biodiesel From Used Kitchen Grease or Waste Vegetable Oil by Mike Pelly This is how to make your own biodiesel fuel from used cooking oil. Please not that you must do a certain amount of safety precautions to make lye and I strongly recommend researching how to make cold process soap prior to attempting to make it. In reality BDG is not pure glycerin. Next, you mix about 1100 grams of sodium hydroxide into the methanol. I am getting free, partially hydrogenated soybean oil and partially hydrogenated cottonseed oil that was used to make donuts. This article is written by Rick Knicely from the Knice-N-Clean Soap Company. Open all the valves in the circuit on the processor and start the pump again so the oil is circulating. The fact that soil conditions matter a lot less with algae means it doesn't have to take up food crop land, or rainforest areas. If you really want to use the byproduct glycerin, I would recommend a more modified, traditional recipe such as: 16 oz. One of the most prominent Biodiesel glycerin soap makers decided a couple years ago to write up a guide on how to make soap from Biodiesel glycerin and offer it to the world. Step two: Build your plant, sized to your feedstock supply. The most frequently asked question Ive gotten this year has got to be about making soap from biodiesel glycerin. Once people have mastered the art of making the soap, the obvious question is can it be sold. Conversion of acid oil to biodiesel as a function of methanol : acid oil weight ratios. Please read up on this before you start, and please understand the chemical dangers involved in this process. In fact, one of our customers has successfully made over 800 bars of soap from the nasty black stuff and then gone a step further and reacted even more of the glycerin into liquid soap. One word: Algae. From pink to yellow to sparkly soap, Ive seen it made into just about every color imaginable and scented in every scent under the sun (my favorite scent is the frankincense and myrrh bars we stock at Christmas time). I am obviously not using it to make any bio diesel so I will be converting it all to soap. -A catalyst: NaOH (sodium hydroxide) or KOH (potassium hydroxide) The difference? Now all you need to do is wash your fuel before you can put it in a car. Finally pour off the biodiesel from the top of the container. It looks gross! I use the glycerin from the bio diesel reaction. 10 years ago Pour the oil into a. Everything from green liquid hand soap to sparkly colored bars to tips & tricks on how to get your soap to do just about anything under the sun are discussed on a regular basis. By adding other whole oils or fatty acids you can add the missing properties to your BDG soaps to create the desired soap you want to create. Hes the author of Making Biodiesel Soaps and is a leading expert on producing high quality, commercial grade soaps from biodiesel glycerin. I personally have been using Biodiesel glycerin soap in the shower for well over a year now and absolutely love it! We also have published a great book, called Making Biodiesel Soaps that covers the ins & outs of making great soaps from biodiesel glycerin. In liquid form, it makes an excellent moisturizing hand cleaner. Generally speaking, biodiesel is an alternative or additive to standard diesel fuel that is made from biological ingredients instead of petroleum (or crude oil). Enter your email address below and you will receive all our new posts directly in your email inbox. . 16 oz. This is probably due to the fact that it is 100% glycerin which is not entirely saponifiable by lye. 4 years ago, How do you get solid fryer Oil to be a liquid, where would i get ethanol online at cheap rates, Reply The rate of reaction was hindered by the decrease in catalyst activity. I answer anywhere between 120 200 emails, every day. No harvesting required. on Introduction. of water for every gallon of glycerin and heat the water to 100 F (38 C). Vegetable oil has many green advantages such as the product biodiesel can be used to supplement energy which can reduce the reliance of non-renewable petroleum. The reaction is complete in about three to five minutes. Image titled Make Lye Soap from Biodiesel By products Step 12 You put in 20% methanol, and get out 20% glycerin. place plastic container in ice bath. personally I have seen plenty of swimming pools and ponds that could use to have some cleaning done at least there the algae could be used rather than just thrown / flushed away if algae harvesting was easy to do. In the photo above, the glycerin is on the right. Do not use any crappy oil that looks like a cloudy mess at the bottom of the oil. If you'd like to use an image, please be a friend and credit the photo and link back to Soap Queen. Do not use the soap until fully cured. I was looking to make more of a shop soap/cleaner soap with this but I know there is a bit of controversy over it. It is both non-toxic and renewable. The soaps ph level should be less then 10. 6. gear up for safety! Reading The Test: I told my wife that the byproducts could be made into soap. The fre e fatty acids in the oil react with the sodium or potassium catalyst to form soaps. UF Biodiesel was producing soap as part of the program to use all by-products. Long sleeves are recommended. If he's making it from WASTE oil, than tell me again how that will drive up food prices? Stir approximately 5.5 oz. 5. Image titled Make Lye Soap from Biodiesel By products Step 7 Weve had several customers report back that after using soap made from Biodiesel glycerin their skin felt softer. Heat the oil to 130 degrees F. (you can open the drain valve, get a quick sample, and use a quick-read thermometer to check. It has what I like to call Saponifiable Elements left over from the biodiesel production process. Reply Like the way it's pushing up the price of foodaround the world, and the fact that producing food crops uses about 2.3 times more fossil fuelenergy to grow than the energy they provide.Looks like I can swap destroying the climate with my car for causing global famine with my car. Available on the market today are several soap making fragrances that can be added to give the soap practically any scent youd like. Only use containers for making biodiesel - don't use them for storing food afterwards, even if you wash them well. Feel free to share, tweet and pin to your hearts content. Method 2 Procedure 1 Add 200 ml methanol to glass blender or mixer. 2) Dissolve some catalyst (NaOH or KOH) and water in a bowl If you really want to use the byproduct glycerin, I would recommend a more modified, traditional recipe such as: 16 oz. For this recipe, you will simply need exactly 2 lbs of lard, 4.4 oz of lye, and 7 fluid oz water. Theres a really good example here: . The answer is whole-heartedlyYES! How Can It Be Used? on Introduction, remember we can always go down or up so we could have tanks stacked on top of eachother 10 stories down and 10 stories up, that would reduse the surface area of the tanks on land by 95%. This is because the bubbles formed by the lather have a lifting effect on the dirt and make it easier to wash away during the cleaning process. This tutorial will get you through the process of making biodiesel, but not the necessary washing process. For example, if your 100 ml of biodiesel weighs 86 grams, take 86g/100ml = 8.60g . You can add flower petals to decorate your soap too! Open the valve nearest the tank and make sure the valve on the other side of the drain is closed, then slowly open the drain valve. Methyl esters is the chemical name for biodiesel and glycerin is used in a variety of products, including soap. Methanol is a harmful alcohol. This Soap Is Amazing! If youd like to learn more about this guide, click here. So, what are you waiting for? ). Add the water and lye mixture to the glycerin. created websites where they sell their soap. We cant think of a better way to get rid of glycerin! Take a carboy filled with oil and connect a section of hose from the carboy to the intake valve on your processor. Plus, the moisturizing attributes of glycerin found in this soap are great for the skin. Another tool you can use is the KNC Soap Calculator which will help you formulate a balanced recipe for your BDG that will give you a nice firm bar soap and/or bar and liquid soap with tons of lather. Some may say that lather is just eye candy for cleaning but that is not totally true. It can do some serious bodily damage. Image titled Make Lye Soap from Biodiesel By products Step 8 Measure the proper amounts of water and lye to be used, heat the water to 100 degrees F., add the lye and mix until all the lye is dissolved. Anybody experienced with this? Steps The Recipe for Converting Grease to Fuel. During this additional drying time, the soap will turn from a dark brown to a lighter tan color. on Introduction. Biodiesel is a mixture of alkyl esters and it can be used in conventional compression ignitions engines, which need almost no modification. You may be thinking or have heard You cant make soap from glycerin, thats impossible! And technically, that is true pure glycerin cannot be made into soap. 5 years ago, 14 years ago Let this go for about an hour before you consolidate it all in the tank. 7 years ago Nows a great time to start getting rid of that glycerin lake sitting out back & turning it into not only something worthwhile to clean with but possibly even a marketable product! Start with more than one. Heat it to 175 F (79 C) if you made your biodiesel from ethanol. We had planned to have UF clubs and organizations use. You'll need a drum containing 45 gallons of oil. This doesnt go into the exact measurements of how its made (it varies based on the type of soap youre making), but we will give you a good idea of just how simple it can be to make this incredible soap. Secondly, it will ensure that all of the ingredients in the BDG are reacted into soap, otherwise you can end up with a soap that feels oily and cleans poorly. F. Keep stirring until the bubbles quit coming up. There's still plenty of ground to cover, but algae is very promising. Measure your lye into a. Close the intake valve.Double check the pressure vent on the processor. 6) Shake the molds back and forth to allow it to settle. Be sure to have primed the pump. The methanol must be removed from your BDG prior to using it to make soap that will come into contact with a person or animal. During the process of rebatching your BDG into soap, you might also want to think about adding other ingredients to add lather or hardness to better balance the soap you make. Simple Steps to Making Biodiesel 1. A plastic storage bin with a lid works well. I filter mine down to 50 microns. Olive Oil 16 oz. DIY Rose Loofah Soap by A Pumpkin and a Princess. One of the most basic things we do when we make Biodiesel is obtain the oil to make it with. Click here to see the discussion forum on soap recipes & more! Once the soap is made, be prepared to make A LOT MORE of it. Image titled Make Lye Soap from Biodiesel By products Step 11 The first step would be to accurately weigh the lard and lye using the scale, and the water using. If you're using more than 5 gallons of oil you obviously will need to disconnect the hose and repeat more than once. Included in our recipe sections are biodiesel glycerin soap recipes that will add hardness and lather to your biodiesel glyceirn bar soap. Open the valve on the carboy and remove the vent cap so there is a slight bit of air coming into the carboy as some of the liquid trickles down the hose. As soon as I add the larger tank I'm adding that and some other upgrade type things. Image titled Make Lye Soap from Biodiesel By products Step 2 Believe it or not, making Biodiesel glycerin based soap is pretty easy. Just be sure to boil off any leftover methanol before you use it. Well,thank you so much for the idea..Thats very interesting topic:D, Pingback: Homemade Acne Cure - 4 Homemade Acne Remedies That Work - Daily Skin Care Tips. Were pretty sure that once you try it youll want more and will be just as hooked on the stuff as we are. Heat the oil to 140F. If youd like to just try a bar of this great soap to see what all the fuss is all about,we have a full line of various bars in different scents that you can purchase right from our website and give it a try. These recipes will have the amout of lye for the biodiesel glycerin split out. So if you think about it, in a way, our BDG is already soap. bucket. Discover Green Science Fair for a Better Planet, Choo-Choo Chairs: a New Life for Boston's Metro Seats, Chevron Pattern Plywood Corner Desk (motorized), Laser Cut Radial Ridgeline Mountain Model. 11. Its true that our BDG soaps clean extremely well out of the box, but with extra lather they can actually perform better too. Regards from South Africa, This section on our website is great for that. The transesterification reaction yields methyl or ethyl esters (biodiesel) and a byproduct of glycerin. You see, this soap can be used for just about anything you can think of. hi sirmy name is ashok kumar mohapatra.i read your article.it is very helpful for me to make my biodiesel projectif u will help me regarding this within low budgetthen i can start my projectthank u. To filter it I just hung a bag filter above a clean 5 gal. This process requires a high alcohol to oil ratio (42:1 mole ratio). Here's a recipe: Optimization of a Batch Type Ethyl Ester Process. Mix these in the same jar. In the next section, well show you how! NOW If youre like most Biodiesel producers, you probably have a lot of glycerin laying around.and, like most of us, youd probably like to find a way to get rid of it all.